Methyl iodide → HCID 21483942, compound

HRID 1415208Notes

Reaction equation

HRID 1415208 reaction equation
[CH:1]1(C2CCC3C(=C(Cl)C(Cl)=C(OC)C=3)C2=O)[CH2:5][CH2:4][CH2:3][CH2:2]1.[CH3:21][O:22][C:23]1[CH:24]=[C:25]2[C:30](=[C:31]([CH3:34])[C:32]=1[CH3:33])[C:29](=[O:35])[CH2:28][CH2:27][CH2:26]2.CI.C1(Br)CCCC1>>[CH:1]1([CH:28]2[CH2:27][CH2:26][C:25]3[C:30](=[C:31]([CH3:34])[C:32]([CH3:33])=[C:23]([O:22][CH3:21])[CH:24]=3)[C:29]2=[O:35])[CH2:5][CH2:4][CH2:3][CH2:2]1

Participants

5

Reactant 4

HCID 6328Methyl iodideHCID 8728BromocyclopentaneHCID 21483925HCID 21483925, compoundHCID 21483939HCID 21483939, compound

Product 1

HCID 21483942HCID 21483942, compound

Procedure

By the procedure of Example III, Step 1, but substituting for the 2-cyclopentyl-6-methoxy-7,8-dichloro- 1-tetralone used therein an euivalent amount of 6-methoxy- 7,8-dimethyl-1-tetralone, and for the methyl iodide there used an equivalent amount of cyclopentyl bromide, then 2-cyclopentyl-6-methoxy-7,8-dimethyl-1-tetralone is obtained.

Sources & evidence

ORD record
ord-3ff2bfe11d874fb9ad2a62b0818e474e
Source dataset
uspto-grants-1977_01
Patent number
US04003927

Reaction notes

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