9-Acetoxyxanthene → N-(N-ethyl-3-pyrrolidinyl)-9-xanthenylamine

HRID 1415548Notes

Reaction equation

HRID 1415548 reaction equation
C(O[CH:5]1[C:18]2[CH:17]=[CH:16][CH:15]=[CH:14][C:13]=2[O:12][C:11]2[C:6]1=[CH:7][CH:8]=[CH:9][CH:10]=2)(=O)C.[NH2:19][CH:20]1[CH2:24][CH2:23][N:22]([CH2:25][CH3:26])[CH2:21]1>C1(C)C=CC=CC=1>[CH2:25]([N:22]1[CH2:23][CH2:24][CH:20]([NH:19][CH:5]2[C:6]3[CH:7]=[CH:8][CH:9]=[CH:10][C:11]=3[O:12][C:13]3[C:18]2=[CH:17][CH:16]=[CH:15][CH:14]=3)[CH2:21]1)[CH3:26]

Participants

4

Reactant 2

HCID 125434549-AcetoxyxantheneHCID 128619421-Ethylpyrrolidin-3-amine

Product 1

HCID 21482885N-(N-ethyl-3-pyrrolidinyl)-9-xanthenylamine

Reagents, catalysts & solvents 1

HCID 1140TolueneSolvent

Procedure

Refluxing 4.0 g. of 9-acetoxyxanthene and 2.05 g. of 3-amino-1-ethylpyrrolidine in 175 ml. of dry toluene for 24 hours, then working up as in Example 1 gives N-(N-ethyl-3-pyrrolidinyl)-9 -xanthenylamine.

Workup

  1. temperatureRefluxing 4.0 g

Sources & evidence

ORD record
ord-4ed82e6054b24ec2923582f192ae784b
Source dataset
uspto-grants-1977_01
Patent number
US04005208

Reaction notes

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