Nitric Acid → HCID 53810261, compound

HRID 1415572Notes

Reaction equation

HRID 1415572 reaction equation
[CH:1]12[CH2:10][CH:7]([CH2:8][CH2:9]1)[CH:6]1[CH:2]2[C:3](=[O:12])[CH2:4][C:5]1=[O:11].[N+:13]([O-])([OH:15])=[O:14]>CCOCC>[N+:13]([CH:4]1[C:3](=[O:12])[CH:2]2[CH:6]([CH:7]3[CH2:10][CH:1]2[CH2:9][CH2:8]3)[C:5]1=[O:11])([O-:15])=[O:14]

Participants

4

Reactant 2

HCID 944Nitric AcidHCID 54427708HCID 54427708, compound

Product 1

HCID 53810261HCID 53810261, compound

Reagents, catalysts & solvents 1

HCID 3283Diethyl EtherSolvent

Procedure

To a stirred suspension of tricyclo [5,2,1,02,6 ] decane-3,5-dione (0.82g; 0.05 mole) in dry ether (8ml.) was added fuming nitric acid (1ml.) at -20° C. After stirring for 1hr. at 20° C the solid was filtered, washed with cold, dry ether and recrystallised from methanol, m.p. 167° C.

Workup

  1. filtrationat 20° C the solid was filtered
  2. washwashed with cold, dry ether
  3. customrecrystallised from methanol, m.p. 167° C.

Sources & evidence

ORD record
ord-c2ff502c853e4dc08edcf6128608b214
Source dataset
uspto-grants-1977_01
Patent number
US04005219

Reaction notes

Loading…