HuagongsheHuagongshe Chemistry Print Report · For research reference only
Methane → rac-(3aR,7aS)-hexahydro-4,7-ethanoindene-1,3-dione
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Methane | HCID 297 | — |
| Reactant | rac-(3aR,4S,7R,7aS)-3a,4,7,7a-tetrahydro-4,7-ethanoindene-1,3-dione | HCID 53663301 | — |
| Product | rac-(3aR,7aS)-hexahydro-4,7-ethanoindene-1,3-dione | HCID 54026023 | — |
Reaction Steps
Reduction of tricyclo [5,2,2,02,6 ] undec-8-ene-3,5-dione over 10% palladinised charcoal as described in example 2a gave the title compound; m.p. (MeOH) 254°- 5° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04005219 |
| Source dataset | uspto-grants-1977_01 |
| ORD ID | ord-2edacc029e0342868c30fca7eff82fe9 |
| Source note | uspto-grants-1977_01 |