Hydrazine → 3,5-Dinitropyridine

HRID 1416650Notes

Reaction equation

HRID 1416650 reaction equation
Cl[C:2]1[C:7]([N+:8]([O-:10])=[O:9])=[CH:6][C:5]([N+:11]([O-:13])=[O:12])=[CH:4][N:3]=1.NN>CO>[N+:11]([C:5]1[CH:4]=[N:3][CH:2]=[C:7]([N+:8]([O-:10])=[O:9])[CH:6]=1)([O-:13])=[O:12]

Participants

4

Reactant 2

HCID 9321HydrazineHCID 757382-Chloro-3,5-dinitropyridine

Product 1

HCID 5980543,5-Dinitropyridine

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

A sample of 2-chloro-3,5-dinitropyridine is dissolved in methanol, hydrazine is added, and the reaction mixture is stirred for 16 hours. The solvent is removed, the residue is dissolved in water, silver acetate is added, and the mixture is heated at reflux for 3 hours. The solution is adjusted to a basic pH, and product is extracted with CHCl3.

Workup

  1. customThe solvent is removed
  2. dissolutionthe residue is dissolved in water
  3. additionsilver acetate is added
  4. temperaturethe mixture is heated
  5. temperatureat reflux for 3 hours
  6. extractionis extracted with CHCl3

Sources & evidence

ORD record
ord-1d5df3ec8a9544d4b960c764c6031878
Source dataset
uspto-grants-1999_06
Patent number
US05914328

Reaction notes

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