Ammonia → HCID 3106275, compound

HRID 1416660Notes

Reaction equation

HRID 1416660 reaction equation
[NH2:1][NH2:2].Cl[C:4]1[C:9]([N+:10]([O-:12])=[O:11])=[CH:8][C:7]([N+:13]([O-:15])=[O:14])=[CH:6][N:5]=1.N>CO>[N+:10]([C:9]1[C:4]([NH:1][NH2:2])=[N:5][CH:6]=[C:7]([N+:13]([O-:15])=[O:14])[CH:8]=1)([O-:12])=[O:11]

Participants

5

Reactant 3

HCID 222AmmoniaHCID 9321HydrazineHCID 757382-Chloro-3,5-dinitropyridine

Product 1

HCID 3106275HCID 3106275, compound

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

Hydrazine (anhydrous, 0.75 ml, 23.9 mmol) was added to a solution of 2-chloro-3,5-dinitro-pyridine (3.42 g, 16.8 mmol) in methanol (25 mL). The resultant mixture was stirred at room temperature overnight. Solvent was evaporated, and the residue was washed with water and methanol several times to remove the impurities. A dark solid powder was obtained (3.0 g). MS (DCI/NH3) m/e: 200 (M+1). 1H NMR(DMSO-d6, 300MHz) δ: 9.25 (m, 1H), 9.06 (m, 1H).

Workup

  1. customSolvent was evaporated
  2. washthe residue was washed with water and methanol several times
  3. customto remove the impurities
  4. customA dark solid powder was obtained (3.0 g)

Sources & evidence

ORD record
ord-4a951b629e7f426b8a9ea3876936656a
Source dataset
uspto-grants-1999_06
Patent number
US05914328

Reaction notes

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