Silver Nitrate → HCID 88301352, compound

HRID 1416758Notes

Reaction equation

HRID 1416758 reaction equation
[Na+].[Na+].[Cl:3][C:4]1[CH:5]=[C:6]([CH:10]([OH:31])[CH2:11][NH:12][CH:13]([CH3:30])[CH2:14][C:15]2[CH:29]=[CH:28][C:18]3[O:19][C:20]([C:25]([O-:27])=[O:26])([C:22]([O-:24])=[O:23])[O:21][C:17]=3[CH:16]=2)[CH:7]=[CH:8][CH:9]=1.[N+]([O-])([O-])=O.[Ag+:36]>O>[Ag+:36].[Ag+:36].[Cl:3][C:4]1[CH:5]=[C:6]([CH:10]([OH:31])[CH2:11][NH:12][CH:13]([CH3:30])[CH2:14][C:15]2[CH:29]=[CH:28][C:18]3[O:19][C:20]([C:22]([O-:24])=[O:23])([C:25]([O-:27])=[O:26])[O:21][C:17]=3[CH:16]=2)[CH:7]=[CH:8][CH:9]=1

Participants

4

Reactant 2

HCID 24470Silver NitrateHCID 15669209HCID 15669209, compound

Product 1

HCID 88301352HCID 88301352, compoundYield 100%

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

To a stirred solution of 5-{2-[2-(3-chlorophenyl)-2-hydroxyethylamino]-propyl}-benzo[1,3]dioxole-2,2-dicarboxylic acid disodium salt (3.0 gm, 6.0 mmol) in distilled water, (in the dark) a solution of AgNO3 (2.3 g, 12.0 mmol) was added dropwise. After stirring at room temperature for 1 h the separated solid was filtered and washed with water and acetone. The solid was dried at room temperature under vacuum to give a colorless solid; yield 100%; mp 183-185; M+H 422.1.

Workup

  1. filtrationwas filtered
  2. washwashed with water and acetone
  3. customThe solid was dried at room temperature under vacuum
  4. customto give a colorless solid

Sources & evidence

ORD record
ord-7308a2270e3e418d91db0e3d85414771
Source dataset
uspto-grants-1999_06
Patent number
US05914339

Reaction notes

Loading…