3,4-Dichlorobenzyl chloride → tert-Butyl [9-(3,4-Dichlorobenzyl)-4-methyl-1-methylthiocarbazol-2-yl]acetate

HRID 1417495Notes

Reaction equation

HRID 1417495 reaction equation
[CH3:1][C:2]1[C:14]2[C:13]3[C:8](=[CH:9][CH:10]=[CH:11][CH:12]=3)[NH:7][C:6]=2[C:5]([S:15][CH3:16])=[C:4]([CH2:17][C:18]([O:20][C:21]([CH3:24])([CH3:23])[CH3:22])=[O:19])[CH:3]=1.[Cl:25][C:26]1[CH:27]=[C:28]([CH:31]=[CH:32][C:33]=1[Cl:34])[CH2:29]Cl>>[Cl:25][C:26]1[CH:27]=[C:28]([CH:31]=[CH:32][C:33]=1[Cl:34])[CH2:29][N:7]1[C:6]2[C:5]([S:15][CH3:16])=[C:4]([CH2:17][C:18]([O:20][C:21]([CH3:24])([CH3:23])[CH3:22])=[O:19])[CH:3]=[C:2]([CH3:1])[C:14]=2[C:13]2[C:8]1=[CH:9][CH:10]=[CH:11][CH:12]=2

Participants

3

Reactant 2

HCID 76093,4-Dichlorobenzyl chlorideHCID 54527372Tert-butyl (4-methyl-1-methylthiocarbazol-2-yl)acetate

Product 1

HCID 67572163tert-Butyl [9-(3,4-Dichlorobenzyl)-4-methyl-1-methylthiocarbazol-2-yl]acetateYield 82%

Procedure

Following a procedure and using relative proportions of starting materials similar to those described in Example 4, but using tert-butyl (4-methyl-1-methylthiocarbazol-2-yl)acetate and 3,4-dichlorobenzyl chloride as starting materials, the title compound was obtained in a yield of 82% as an oil.

Sources & evidence

ORD record
ord-a1369f68777b40aca5b77a5e12b61a8d
Source dataset
uspto-grants-1999_03
Patent number
US05877199

Reaction notes

Loading…