HRID141825

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID175

Acetate

C2H3O2-

3 次

HCID6344

Dichloromethane

CH2Cl2

HCID12192

Ethyl diazoacetate

C4H6N2O2

HCID167511

Rhodium(3+)

Rh+3

结构：C=Cc1ccc(N2CC(=O)N(CC[Si](C)(C)C)S2(=O)=O)c(OCc2ccccc2)c1

HCID66756542

未命名化合物

PRODUCTS

生成物

结构：CCOC(=O)C1CC1c1ccc(N2CC(=O)N(CC[Si](C)(C)C)S2(=O)=O)c(OCc2ccccc2)c1

HCID68839918

未命名化合物

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-867ae989b7c84394b2eed5d800d4af78
来源数据集: Training data from https://doi.org/10.1039/C8SC04228D (9/10)
DOI: 10.1039/C8SC04228D
来源说明: Training data from https://doi.org/10.1039/C8SC04228D (9/10)

反应 SMILES

[C:42]([O-:43])(=[O:44])[CH3:45].[C:47]([O-:48])(=[O:49])[CH3:50].[C:51]([O-:52])(=[O:53])[CH3:54].[CH2:1]([c:2]1[cH:3][cH:4][cH:5][cH:6][cH:7]1)[O:8][c:9]1[c:10]([N:17]2[CH2:18][C:19](=[O:30])[N:20]([CH2:24][CH2:25][Si:26]([CH3:27])([CH3:28])[CH3:29])[S:21]2(=[O:22])=[O:23])[cH:11][cH:12][c:13]([CH:15]=[CH2:16])[cH:14]1.[CH2:39]([Cl:40])[Cl:41].[N+:31](=[N-:32])=[CH:33][C:34](=[O:35])[O:36][CH2:37][CH3:38].[Rh+3:46]>>[CH2:1]([c:2]1[cH:3][cH:4][cH:5][cH:6][cH:7]1)[O:8][c:9]1[c:10]([N:17]2[CH2:18][C:19](=[O:30])[N:20]([CH2:24][CH2:25][Si:26]([CH3:27])([CH3:28])[CH3:29])[S:21]2(=[O:22])=[O:23])[cH:11][cH:12][c:13]([CH:15]2[CH2:16][CH:33]2[C:34](=[O:35])[O:36][CH2:37][CH3:38])[cH:14]1