HuagongsheHuagongshe Chemistry Print Report · For research reference only
4-cyano-4-(3-iodophenyl)-3,4,5,6-tetrahydro-2H-pyran → 4-cyano-4-(3-triisopropylsilylthiophenyl)-3,4,5,6-tetrahydro-2H-pyran
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 4-cyano-4-(3-iodophenyl)-3,4,5,6-tetrahydro-2H-pyran | HCID 11771377 | — |
| Reactant | (2SR,4RS)-4-cyano-2-methyl-4-(3-triisopropylsilylthiophenyl)-3,4,5,6-tetrahydro-2H-pyran | HCID 18786333 | — |
| Product | 4-cyano-4-(3-triisopropylsilylthiophenyl)-3,4,5,6-tetrahydro-2H-pyran | HCID 11360872 | — |
Reaction Steps
The titled compound was prepared according to the procedure described in example 29C for the preparation of (2SR,4RS)-4-cyano-2-methyl-4-(3-triisopropylsilylthiophenyl)-3,4,5,6-tetrahydro-2H-pyran using 4-cyano-4-(3-iodophenyl)-3,4,5,6-tetrahydro-2H-pyran in place of (2SR,4RS)-4-cyano-4-(3-iodophenyl)-2-methyl-3,4,5,6-tetrahydro-2H-pyran.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05883106 |
| Source dataset | uspto-grants-1999_03 |
| ORD ID | ord-a510672ef87245bba103222d130fd591 |
| Source note | uspto-grants-1999_03 |