HuagongsheHuagongshe Chemistry Print Report · For research reference only
Acetate → HCID 15864470, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Acetate | HCID 175 | — |
| Reactant | HCID 22174048 | HCID 22174048 | — |
| Reactant | HCID 53961483 | HCID 53961483 | — |
| Reactant | HCID 54505037 | HCID 54505037 | — |
| Product | HCID 15864470 | HCID 15864470 | — |
Reaction Steps
1H NMR analysis indicated 5-acetoxyhexyl tosylate as the sole product, and hydrolysis of the acetate, conversion of the resulting 5-hydroxyhexyl tosylate to the α-methoxy-α-trifluoromethylphenylacetate (using the corresponding optically pure acid chloride), 1H NMR analysis and comparison to the racemate indicated 78% ee for 5-acetoxyhexyl tosylate.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05886214 |
| Source dataset | uspto-grants-1999_03 |
| ORD ID | ord-6e984ae818d747b184f74fbab18aa8ca |
| Source note | uspto-grants-1999_03 |