2,7-Dibromo-9,9,10,10-tetrafluoro-9,10-dihydrophenanthrene → 9,10-Difluoro-2,7-dihexylphenanthrene

HRID 1419647Notes

Reaction equation

HRID 1419647 reaction equation
[F:1][C:2]1[C:3]2[C:8]([C:9]3[CH:10]=[CH:11][C:12](Br)=[CH:13][C:14]=3[C:15]=1[F:16])=[CH:7][CH:6]=[C:5](Br)[CH:4]=2.F[C:20]1(F)[C:33](F)(F)[C:32]2C=C(Br)C=CC=2C2[C:21]1=[CH:22][C:23](Br)=CC=2>>[F:1][C:2]1[C:3]2[C:8]([C:9]3[CH:10]=[CH:11][C:12]([CH2:4][CH2:3][CH2:2][CH2:15][CH2:14][CH3:9])=[CH:13][C:14]=3[C:15]=1[F:16])=[CH:7][CH:6]=[C:5]([CH2:32][CH2:33][CH2:20][CH2:21][CH2:22][CH3:23])[CH:4]=2

Participants

3

Reactant 2

HCID 153898342,7-Dibromo-9,9,10,10-tetrafluoro-9,10-dihydrophenanthreneHCID 544711629,10-Difluoro-2,7-dibromophenanthrene

Product 1

HCID 541438089,10-Difluoro-2,7-dihexylphenanthrene

Procedure

In analogy to Examples 1 and 2, 9,10-difluoro-2,7-dibromophenanthrene and 9,9,10,10-tetrafluoro-2,7-dibromo-9,10-dihydrophenanthrene can be reacted with other Grignard reagents to give symmetrically substituted compounds of the formula (Ia1) and (Ia2).

Workup

  1. customto give symmetrically substituted compounds of the formula (Ia1) and (Ia2)

Sources & evidence

ORD record
ord-4d418d94ff904ba4b69e32d0a0322e59
Source dataset
uspto-grants-1999_03
Patent number
US05888422

Reaction notes

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