HuagongsheHuagongshe Chemistry Print Report · For research reference only
9,9,10,10-Tetrafluoro-2-bromo-7-octyl-9,10-dihydrophenanthrene → 9,9,10,10-Tetrafluoro-2-hexyl-7-octyl-9,10-dihydrophenanthrene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 9,9,10,10-Tetrafluoro-2-bromo-7-octyl-9,10-dihydrophenanthrene | HCID 53675155 | — |
| Reactant | HCID 178444609 | HCID 178444609 | — |
| Product | 9,9,10,10-Tetrafluoro-2-hexyl-7-octyl-9,10-dihydrophenanthrene | HCID 54136379 | — |
Reaction Steps
In analogy to Example 1, from 9,9,10,10-tetrafluoro-2-bromo-7-octyl-9,10-dihydrophenanthrene and hexylmagnesium bromide. The catalyst used is 1,3-bis(diphenylphosphine)propanenickel(l I) chloride. Chromatography gives 9,9,10,10-tetrafluoro-2-hexyl-7-octyl-9,10-dihydrophenanthrene
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05888422 |
| Source dataset | uspto-grants-1999_03 |
| ORD ID | ord-275799dc2db1403bbb25b7364d218c85 |
| Source note | uspto-grants-1999_03 |