HuagongsheHuagongshe Chemistry Print Report · For research reference only
9,10-Difluoro-2-bromo-7-octylphenanthrene → 9,10-Difluoro-2-hexyl-7-octylphenanthrene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 9,10-Difluoro-2-bromo-7-octylphenanthrene | HCID 54084199 | — |
| Reactant | HCID 178444609 | HCID 178444609 | — |
| Product | 9,10-Difluoro-2-hexyl-7-octylphenanthrene | HCID 53665512 | — |
Reaction Steps
In analogy to Example 2, from 9,10-difluoro-2-bromo-7-octylphenanthrene and 10 mmol of hexylmagnesium bromide. The catalyst used is 0.2 mmol of 1,3-bis(diphenylphosphine)propanenickel(lI) chloride. Chromatography gives 9,10-difluoro-2-hexyl-7-octylphenanthrene.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05888422 |
| Source dataset | uspto-grants-1999_03 |
| ORD ID | ord-c2632c3f02294a9f8820667c0bf2c9c5 |
| Source note | uspto-grants-1999_03 |