(6-Butoxypyridin-3-yl)boronic acid → 2-Butoxy-5-(9,9,10,10-tetrafluoro-7-hexyl-9,10-dihydro-phenanthrene-2-yl)pyridine

HRID 1419654Notes

Reaction equation

HRID 1419654 reaction equation
[F:1][C:2]1([F:25])[C:15]([F:17])([F:16])[C:14]2[CH:13]=[C:12](Br)[CH:11]=[CH:10][C:9]=2[C:8]2[C:3]1=[CH:4][C:5]([CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH3:24])=[CH:6][CH:7]=2.[CH2:26]([O:30][C:31]1[CH:36]=[CH:35][C:34](B(O)O)=[CH:33][N:32]=1)[CH2:27][CH2:28][CH3:29]>>[CH2:26]([O:30][C:31]1[CH:36]=[CH:35][C:34]([C:12]2[CH:11]=[CH:10][C:9]3[C:8]4[C:3](=[CH:4][C:5]([CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH3:24])=[CH:6][CH:7]=4)[C:2]([F:25])([F:1])[C:15]([F:17])([F:16])[C:14]=3[CH:13]=2)=[CH:33][N:32]=1)[CH2:27][CH2:28][CH3:29]

Participants

3

Reactant 2

HCID 45116227(6-Butoxypyridin-3-yl)boronic acidHCID 537437439,9,10,10-Tetrafluoro-2-bromo-7-hexyl-9,10-dihydrophenanthrene

Product 1

HCID 540844382-Butoxy-5-(9,9,10,10-tetrafluoro-7-hexyl-9,10-dihydro-phenanthrene-2-yl)pyridine

Procedure

From 9,9,10,10-tetrafluoro-2-bromo-7-hexyl-9,10-dihydrophenanthrene and 2-butoxypyridine-5-boronic acid in analogy to Example 7.

Sources & evidence

ORD record
ord-a1798208d5fe46359c80c44b0364c05f
Source dataset
uspto-grants-1999_03
Patent number
US05888422

Reaction notes

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