HuagongsheHuagongshe Chemistry Print Report · For research reference only
2,4-Dichloroaniline → 2-Benzothiazolamine, dichloro-
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 2,4-Dichloroaniline | HCID 11123 | — |
| Reactant | Bromine | HCID 24408 | — |
| Reactant | Sodium thiocyanate | HCID 516871 | — |
| Solvent | Acetic Acid | HCID 176 | — |
| Product | 2-Benzothiazolamine, dichloro- | HCID 112722 | — |
Reaction Steps
197 g (1.23 mol) of bromine were slowly added dropwise, while cooling with ice, to a solution of 200 g (1.23 mol) of 2,4-dichloroaniline and 200 g (2.46 mol) of sodium thiocyanate in 1.5 1 of glacial acetic acid. Stirring was carried out for 16 hours at about 20° C., after which the solid was separated off and washed with 10% strength sodium hydroxide solution and water.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05888940 |
| Source dataset | uspto-grants-1999_03 |
| ORD ID | ord-0ccdfe601ca34f66adb31452192eb659 |
| Source note | uspto-grants-1999_03 |