Carbon Dioxide → HCID 131721834, compound

HRID 1420465Notes

Reaction equation

[C:1](=[O:3])=[O:2].[CH2:4]([OH:69])[C@H:5]1[O:10][C@@H:9]2[O:11][C@H:12]3[C@H:17]([OH:18])[C@@H:16]([OH:19])[C@@H:15]([O:20][C@H:21]4[C@H:26]([OH:27])[C@@H:25]([OH:28])[C@@H:24]([O:29][C@H:30]5[C@H:35]([OH:36])[C@@H:34]([OH:37])[C@@H:33]([O:38][C@H:39]6[C@H:44]([OH:45])[C@@H:43]([OH:46])[C@@H:42]([O:47][C@H:48]7[C@H:54]([OH:55])[C@@H:53]([OH:56])[C@@H:51]([O:52][C@H:6]1[C@H:7]([OH:68])[C@H:8]2[OH:67])[O:50][C@@H:49]7[CH2:57][OH:58])[O:41][C@@H:40]6[CH2:59][OH:60])[O:32][C@@H:31]5[CH2:61][OH:62])[O:23][C@@H:22]4[CH2:63][OH:64])[O:14][C@@H:13]3[CH2:65][OH:66]>>[C:1](=[O:3])=[O:2].[CH2:59]([OH:60])[C@H:40]1[O:41][C@@H:42]2[O:47][C@H:48]3[C@H:54]([OH:55])[C@@H:53]([OH:56])[C@@H:51]([O:52][C@H:6]4[C@H:7]([OH:68])[C@@H:8]([OH:67])[C@@H:9]([O:11][C@H:12]5[C@H:17]([OH:18])[C@@H:16]([OH:19])[C@@H:15]([O:20][C@H:21]6[C@H:26]([OH:27])[C@@H:25]([OH:28])[C@@H:24]([O:29][C@H:30]7[C@H:35]([OH:36])[C@@H:34]([OH:37])[C@@H:33]([O:38][C@H:39]1[C@H:44]([OH:45])[C@H:43]2[OH:46])[O:32][C@@H:31]7[CH2:61][OH:62])[O:23][C@@H:22]6[CH2:63][OH:64])[O:14][C@@H:13]5[CH2:65][OH:66])[O:10][C@@H:5]4[CH2:4][OH:69])[O:50][C@@H:49]3[CH2:57][OH:58]

Participants

Reactant 2

HCID 280Carbon Dioxide

HCID 444913Alpha-Cyclodextrin

Product 1

HCID 131721834HCID 131721834, compound

Procedure

100 ml of saturated α-cyclodextrin solution (about 12%) were incubated for 7 days at room temperature under 7 atmospheres carbon dioxide in a 20 cc autoclave. The crystalline adduct could be drawn off, washed with cold water and dried via calcium chloride in the exsiccator.

Workup

washwashed with cold water
dry with materialdried via calcium chloride in the exsiccator

Sources & evidence

ORD record: ord-77293585128643199cac7adf27e025f9
Source dataset: uspto-grants-2000_06
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US06071496

Reaction notes

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