Isopentane → Isopentane alpha-cyclodextrin

HRID 1420468Notes

Reaction equation

[CH2:1]([OH:66])[C@H:2]1[O:7][C@@H:6]2[O:8][C@H:9]3[C@H:14]([OH:15])[C@@H:13]([OH:16])[C@@H:12]([O:17][C@H:18]4[C@H:23]([OH:24])[C@@H:22]([OH:25])[C@@H:21]([O:26][C@H:27]5[C@H:32]([OH:33])[C@@H:31]([OH:34])[C@@H:30]([O:35][C@H:36]6[C@H:41]([OH:42])[C@@H:40]([OH:43])[C@@H:39]([O:44][C@H:45]7[C@H:51]([OH:52])[C@@H:50]([OH:53])[C@@H:48]([O:49][C@H:3]1[C@H:4]([OH:65])[C@H:5]2[OH:64])[O:47][C@@H:46]7[CH2:54][OH:55])[O:38][C@@H:37]6[CH2:56][OH:57])[O:29][C@@H:28]5[CH2:58][OH:59])[O:20][C@@H:19]4[CH2:60][OH:61])[O:11][C@@H:10]3[CH2:62][OH:63].[CH3:67][CH2:68][CH:69]([CH3:71])[CH3:70]>>[CH3:67][CH2:68][CH:69]([CH3:71])[CH3:70].[CH2:56]([OH:57])[C@H:37]1[O:38][C@@H:39]2[O:44][C@H:45]3[C@H:51]([OH:52])[C@@H:50]([OH:53])[C@@H:48]([O:49][C@H:3]4[C@H:4]([OH:65])[C@@H:5]([OH:64])[C@@H:6]([O:8][C@H:9]5[C@H:14]([OH:15])[C@@H:13]([OH:16])[C@@H:12]([O:17][C@H:18]6[C@H:23]([OH:24])[C@@H:22]([OH:25])[C@@H:21]([O:26][C@H:27]7[C@H:32]([OH:33])[C@@H:31]([OH:34])[C@@H:30]([O:35][C@H:36]1[C@H:41]([OH:42])[C@H:40]2[OH:43])[O:29][C@@H:28]7[CH2:58][OH:59])[O:20][C@@H:19]6[CH2:60][OH:61])[O:11][C@@H:10]5[CH2:62][OH:63])[O:7][C@@H:2]4[CH2:1][OH:66])[O:47][C@@H:46]3[CH2:54][OH:55]

Participants

Reactant 2

HCID 6556Isopentane

HCID 444913Alpha-Cyclodextrin

Product 1

HCID 131721835Isopentane alpha-cyclodextrin

Procedure

20 ml of saturated α-cyclodextrin solution were mixed with 1 ml of isopentane and ultrasounded for 3 minutes in the ultrasonic bath. The resulting difficultly soluble complex was obtained through filtration and dried via calcium chloride.

Workup

customThe resulting difficultly soluble complex was obtained through filtration
dry with materialdried via calcium chloride

Sources & evidence

ORD record: ord-654bed1612b04b9d917bf465415e688e
Source dataset: uspto-grants-2000_06
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US06071496

Reaction notes

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