HuagongsheHuagongshe Chemistry Print Report · For research reference only
Ethylenediamine → HCID 18783142, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Ethylenediamine | HCID 3301 | — |
| Reactant | Nitromethane | HCID 6375 | — |
| Reactant | 3,3,5,5-Tetramethylcyclohexanone | HCID 84399 | — |
| Product | HCID 18783142 | HCID 18783142 | 61% |
Reaction Steps
A solution of 3,3,5,5-tetramethylcyclohexanone (2-13) (1.54 g, 10 mmol) and ethylenediamine (60 mg) in nitromethane (45 ml) was refluxed in argon atmosphere for 25 h. Excess of nitromethane was then removed in vacuo and the residue was purified by flash chromatography on silica gel, eluting with hexane-ethyl acetate (6:1). 1.2 g (61%) of 6 was obtained as an oil.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06071966 |
| Source dataset | uspto-grants-2000_06 |
| ORD ID | ord-b4bb1bc1af6944428d818ec8bee00cd8 |
| Source note | uspto-grants-2000_06 |