Acetone → Cyclohexanol

Participants

Reaction Steps

After adding FeCl2 ·4H2O (0.5 g), Pd/alumina(Pd content 1%, 1 g) and cyclohexane (5 g) to the mixture of acetone (17 ml) and acetic acid (3 ml), it was stirred in a flow of hydrogen and oxygen gases at the respective rate of 20 ml/min. As the result of reaction for 17 hours at 30° C. under atmospheric pressure, 8.84 mole % of cyclohexanol and 2.13 mole % cyclohexanone with the total yield of 10.97 mole % were obtained.

Provenance & Evidence