HuagongsheHuagongshe Chemistry Print Report · For research reference only
HCID 67069097, compound → HCID 59829820, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | HCID 67069097 | HCID 67069097 | — |
| Catalyst | HCID 178418406 | HCID 178418406 | — |
| Solvent | Dichloromethane | HCID 6344 | — |
| Product | HCID 59829820 | HCID 59829820 | 72.2% |
Reaction Steps
A flask was charged with 2,4-bis-benzyloxy-5-bromobenzyl alcohol (10.5 g; 26 mmol), manganese dioxide (45 g; 0.520 mol), and dichloromethane (250 mL). The reaction was stirred at reflux for three days. The slurry was then filtered through celite, and evaporated to give 2,4-bis-benzyloxy-5-bromobenzaldehyde (7.46 g; 18.77 mmol).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08927548B2 |
| Source dataset | uspto-grants-2015_01 |
| ORD ID | ord-6b409ccea974451497019f550f3b467b |
| Source note | uspto-grants-2015_01 |