(1,1'-Biphenyl)-4-methanol → [1,1′-Biphenyl]-4-ylmethyl 2-propenoate

HRID 1424306Notes

Reaction equation

HRID 1424306 reaction equation
C1([C:7]2C=CC=C[C:8]=2[CH2:9][OH:10])C=CC=CC=1.[C:15]1([C:21]2[CH:28]=[CH:27][C:24]([CH2:25][OH:26])=[CH:23][CH:22]=2)[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=1>>[C:9]([O:26][CH2:25][C:24]1[CH:23]=[CH:22][C:21]([C:15]2[CH:16]=[CH:17][CH:18]=[CH:19][CH:20]=2)=[CH:28][CH:27]=1)(=[O:10])[CH:8]=[CH2:7]

Participants

3

Reactant 2

HCID 19186(1,1'-Biphenyl)-4-methanolHCID 76229(1,1'-Biphenyl)-2-methanol

Product 1

HCID 15621059[1,1′-Biphenyl]-4-ylmethyl 2-propenoate

Procedure

The same process as in Synthetic Example 1 was conducted except that the ortho-phenylbenzyl alcohol in Synthetic Example 1 was changed to para-phenylbenzyl alcohol. Consequently, 22.4 g of para-phenylbenzyl acrylate was obtained. The obtained para-phenylbenzyl acrylate was solid at ordinary temperature and had a melting point of 32° C. and a refractive index of 1.5920 at 40° C. The measurement result of 1H-NMR is shown below.

Sources & evidence

ORD record
ord-28495399db494d2bbb0e9b12e16f33bf
Source dataset
uspto-grants-2015_01
Patent number
US08927650B2

Reaction notes

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