Allyl bromide → HCID 131732250, compound

Participants

Reaction Steps

Compound 15 was synthesized as described above for compound 14, reflux time 3 h. Allyl bromide (1.97 g, 16.28 mmol), compound 4 (1.0 g, 1.42 mmol). The target compound was isolated as a bright yellow solid. Yield: 0.48 g, 42%. 1H NMR (D2O, 400 MHz): δ (ppm) 9.21-9.23 (4H, d), 9.14-9.16 (4H, d), 8.601 (8H, m), 7.68 (4H, s), 6.19-6.26 (2H, m), 6.03 (4H, s), 5.57-5.67 (2H, quad), 5.37-5.39 (2H, d). 13C NMR (D2O, 100 MHz): δ (ppm) 153.48, 153.04, 148.70, 148.66, 148.65, 148.63, 148.52, 148.46, 148.38, 136.95, 133.21, 132.33, 130.13, 129.89, 126.60, 67.01, 66.54.

Provenance & Evidence