HRID1424696

反应详情

EQUATION

反应方程式

REACTANTS

反应物

$结构：CC/C=C\CC[C@@H](O)C/C=C\CCCCCCCC(=O)O$

HCID5312831

未命名化合物

$结构：CC/C=C\CCC(O)C/C=C\CCCCCCCCCC(=O)O$

HCID73242169

未命名化合物

PRODUCTS

生成物

$结构：CCCCCC[C@@H](O)C/C=C\CCCCCCCC(=O)O$

HCID643684

(9Z,12R)-12-Hydroxyoctadec-9-enoic acid

C18H34O3

$结构：CCCCCC[C@@H](O)C/C=C\CCCCCCCCCC(=O)O$

HCID5312810

Lesquerolic acid

C20H38O3

PROCEDURE

实验过程

The process is particularly advantageous for feedstocks comprising densipolic acid and auricolic acid, as or not as a mixture with ricinoleic acid and lesquerolic acid, as, after hydrogenation, saturated acids having the same C18 or C20 chain length are obtained.

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-4d3346640814456687bdcb34cbbbc9b3
来源数据集: uspto-grants-2015_01
DOI: 10.6084/m9.figshare.5104873.v1
专利: US08927746B2
来源说明: uspto-grants-2015_01

反应 SMILES

[CH3:1][CH2:2]/[CH:3]=[CH:4]\[CH2:5][CH2:6][C@@H:7]([OH:21])[CH2:8]/[CH:9]=[CH:10]\[CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][C:18]([OH:20])=[O:19].[CH3:22][CH2:23]/[CH:24]=[CH:25]\[CH2:26][CH2:27][CH:28]([OH:44])[CH2:29]/[CH:30]=[CH:31]\[CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH2:39][CH2:40][C:41]([OH:43])=[O:42]>>[C:18]([OH:20])(=[O:19])[CH2:17][CH2:16][CH2:15][CH2:14][CH2:13][CH2:12][CH2:11]/[CH:10]=[CH:9]\[CH2:8][C@@H:7]([CH2:6][CH2:5][CH2:4][CH2:3][CH2:2][CH3:1])[OH:21].[CH3:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][C@@H:28]([OH:44])[CH2:29]/[CH:30]=[CH:31]\[CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH2:39][CH2:40][C:41]([OH:43])=[O:42]