Sodium (E)-2-((2E,4E)-3-(2-Carboxyethyl)-5-(5-chloro-3,3-dimethyl-7-(3-sulfonatopropyl)-3H-pyrrolo[2,3-b]pyridin-7-ium-2-yl)penta-2,4-dienylidene)-3,3-dimethyl-1-(3-sulfonatopropyl)indoline-5-sulfonate → Sodium (E)-2-((E)-3-((E)-2-(5-Chloro-3,3-dimethyl-7-(3-sulfonatopropyl)-3H-pyrrolo[2,3-b]pyridin-7-ium-2-yl)vinyl)-6-(2,5-dioxopyrrolidin-1-yloxy)-6-oxohex-2-enylidene)-3,3-dimethyl-1-(3-sulfonatopropyl)indoline-5-sulfonate
Reaction equation
ClC1C=C2C(C)(C)/C(=C\C=C(/C3C=CC=C(CCCCC(O[N:70]4[C:74](=[O:75])[CH2:73][CH2:72][C:71]4=[O:76])=O)C=3)\C=C\C3C(C)(C)C4C5C=C(S([O-])(=O)=O)C=C(S([O-])(=O)=O)C=5C=CC=4[N+]=3CCCCS([O-])(=O)=O)/N=C2N(CCCCS([O-])(=O)=O)C=1.[Na+:77].[Na+].[Na+].[C:80]([CH2:83][CH2:84]/[C:85](/[CH:110]=[CH:111]/[C:112]1[C:113]([CH3:130])([CH3:129])[C:114]2[C:115]([N:128]=1)=[N+:116]([CH2:121][CH2:122][CH2:123][S:124]([O-:127])(=[O:126])=[O:125])[CH:117]=[C:118]([Cl:120])[CH:119]=2)=[CH:86]\[CH:87]=[C:88]1\[N:89]([CH2:103][CH2:104][CH2:105][S:106]([O-:109])(=[O:108])=[O:107])[C:90]2[C:95]([C:96]\1([CH3:98])[CH3:97])=[CH:94][C:93]([S:99]([O-:102])(=[O:101])=[O:100])=[CH:92][CH:91]=2)([OH:82])=[O:81].[Na+].[Na+]>>[Cl:120][C:118]1[CH:119]=[C:114]2[C:113]([CH3:130])([CH3:129])[C:112](/[CH:111]=[CH:110]/[C:85](/[CH2:84][CH2:83][C:80]([O:82][N:70]3[C:74](=[O:75])[CH2:73][CH2:72][C:71]3=[O:76])=[O:81])=[CH:86]/[CH:87]=[C:88]3/[N:89]([CH2:103][CH2:104][CH2:105][S:106]([O-:109])(=[O:107])=[O:108])[C:90]4[C:95]([C:96]/3([CH3:97])[CH3:98])=[CH:94][C:93]([S:99]([O-:102])(=[O:100])=[O:101])=[CH:92][CH:91]=4)=[N:128][C:115]2=[N+:116]([CH2:121][CH2:122][CH2:123][S:124]([O-:127])(=[O:126])=[O:125])[CH:117]=1.[Na+:77].[Na+:77]Participants
3
Reactant 2
Product 1
Procedure
Compound 36 is prepared analogously to compound 29 (Example 38), except that compound 19 is used as a starting material.
Sources & evidence
- ORD record
- ord-d21730a9ca2644d9a0530657686d4b85
- Source dataset
- uspto-grants-2015_01
- Patent number
- US08927719B2
Reaction notes
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