HuagongsheHuagongshe Chemistry Print Report · For research reference only
Toluene → HCID 69085944, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Toluene | HCID 1140 | — |
| Reactant | Diisobutylamine | HCID 8085 | — |
| Reactant | HCID 86695882 | HCID 86695882 | — |
| Solvent | Water | HCID 962 | — |
| Product | HCID 69085944 | HCID 69085944 | 3.9% |
Reaction Steps
1.0 g (7.75 mmoles) of diisobutyl amine is dropped into a toluene solution of 7-methyl-9-oxo-9H-thioxanthene-1-carbonyl chloride (0.22 g, 0.78 mmoles). After 2 hours at room temperature under stirring, the mixture is poured in water, the organic phase is separated and washed with water. A crude oil is obtained after evaporation of the solvent. 11.5 mg of a yellow solid are isolated by flash chromatography of the crude oil (SiO2— eluent: CH2Cl2:MeOH 96:4).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08933142B2 |
| Source dataset | uspto-grants-2015_01 |
| ORD ID | ord-ee35678b093b4d4e852c839682ae4670 |
| Source note | uspto-grants-2015_01 |