Benzene → Cinnamoylbenzene

HRID 1428434Notes

Reaction equation

HRID 1428434 reaction equation
[CH:1]1[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[C:7](Cl)(=[O:16])[CH:8]=[CH:9][C:10]1[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=1.[Cl-].[Al+3].[Cl-].[Cl-]>C(=S)=S>[C:7]([C:1]1[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1)(=[O:16])[CH:8]=[CH:9][C:10]1[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=1

Participants

5

Reactant 3

HCID 241BenzeneHCID 660233-Phenylprop-2-enoyl chlorideHCID 6451240Aluminum(III) Chloride

Product 1

HCID 7189Cinnamoylbenzene

Reagents, catalysts & solvents 1

HCID 6348Carbon DisulfideSolvent

Procedure

Benzene (1 mL), cinnamoyl chloride (0.160 mg), and aluminium chloride (150 mg) were reacted in carbon disulfide (5 mL) at from 0° C. to room temperature for 2 hours. The resultant was treated in the same manner as described in Example 1 to obtain the title compound (35 mg).

Workup

  1. additionThe resultant was treated in the same manner

Sources & evidence

ORD record
ord-e650b34d730148efae6ccd2b4ebd8136
Source dataset
uspto-grants-2015_01
Patent number
US08937091B2

Reaction notes

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