Benzene → HCID 11217410, compound

HRID 1428446Notes

Reaction equation

HRID 1428446 reaction equation
[CH:1]1[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[C:7](Cl)(=[O:11])/[CH:8]=[CH:9]/[CH3:10].[Cl-].[Al+3].[Cl-].[Cl-].Cl[CH2:18]Cl>>[CH3:18][C:1]1[CH:6]=[CH:5][C:4]([C:7](=[O:11])/[CH:8]=[CH:9]/[CH3:10])=[CH:3][CH:2]=1

Participants

5

Reactant 4

HCID 241BenzeneHCID 6344DichloromethaneHCID 643131trans-Crotonyl chlorideHCID 6451240Aluminum(III) Chloride

Product 1

HCID 11217410HCID 11217410, compound

Procedure

Benzene (1 mL), crotonoyl chloride (236 mg), and aluminium chloride (160 mg) were reacted in dichloromethane (1.5 mL) at from 0° C. to room temperature for 4 hours. The resultant was treated in the same manner as described in Example 1 to obtain the title compound (126 mg).

Workup

  1. additionThe resultant was treated in the same manner

Sources & evidence

ORD record
ord-b1c908791f464c7eb1599372462327ae
Source dataset
uspto-grants-2015_01
Patent number
US08937091B2

Reaction notes

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