HuagongsheHuagongshe Chemistry Print Report · For research reference only
1-Chloronaphthalene → 1-(5-Chloro-2-naphthalenyl)-2-propen-1-one
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1-Chloronaphthalene | HCID 7003 | — |
| Reactant | Acryloyl chloride | HCID 13140 | — |
| Reactant | Aluminum(III) Chloride | HCID 6451240 | — |
| Solvent | Dichloromethane | HCID 6344 | — |
| Product | 1-(5-Chloro-2-naphthalenyl)-2-propen-1-one | HCID 86673231 | 113.6% |
Reaction Steps
1-chloronaphthalene (183 mg), acryloyl chloride (120 mg), and aluminium chloride (150 mg) were reacted in dichloromethane (1.5 mL) at from −40° C. to room temperature for 2 hours. The resultant was treated in the same manner as described in Example 1 to obtain the title compound (277 mg).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08937091B2 |
| Source dataset | uspto-grants-2015_01 |
| ORD ID | ord-157d8eeeec514dfcb7d27766edf2eada |
| Source note | uspto-grants-2015_01 |