2-(Tributylstannyl)pyridine → HCID 59631221, compound

Participants

Reaction Steps

The chlorides were prepared according to Procedure E using 8-bromo-2,4-dichloro-3-methylquinoline (0.32 g, 1.11 mmol), 2-(tributylstannyl)pyridine (0.45 mL, 1.23 mmol) and palladium tetrakistriphenylphosphine (0.13 g, 0.11 mmol) in toluene (2.2 mL) to give 8-bromo-4-chloro-3-methyl-2-(pyridin-2-yl)quinoline and further elution gave 4-chloro-3-methyl-2,8-di(pyridin-2-yl)quinoline as a white solid. Mass Spectrum (ESI) m/e=332.0 (M+1).

Provenance & Evidence