HuagongsheHuagongshe Chemistry Print Report · For research reference only
Methyl iodide → Methyl 3-bromo-5-nitrobenzoate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Methyl iodide | HCID 6328 | — |
| Reactant | Potassium Carbonate | HCID 11430 | — |
| Reactant | 3-Bromo-5-nitrobenzoic acid | HCID 239336 | — |
| Solvent | Dimethylformamide | HCID 6228 | — |
| Product | Methyl 3-bromo-5-nitrobenzoate | HCID 239341 | — |
Reaction Steps
Prepared according to Procedure S using 3-bromo-5-nitrobenzoic acid (5.0 g, 20.32 mmol), potassium carbonate (5.62 g, 40.6 mmol), DMF (55 mL), and methyl iodide (2.54 mL, 40.6 mmol) to afford methyl 3-bromo-5-nitrobenzoate as an orange amorphous solid. Mass Spectrum (ESI) m/e=261.1 (M+1).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08940724B2 |
| Source dataset | uspto-grants-2015_01 |
| ORD ID | ord-689a289ea715465ea461f74228598252 |
| Source note | uspto-grants-2015_01 |