HuagongsheHuagongshe Chemistry Print Report · For research reference only
Hydrochloric Acid → Allylethylamine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Hydrochloric Acid | HCID 313 | — |
| Reactant | tert-Butyl ethyl(prop-2-en-1-yl)carbamate | HCID 71365398 | — |
| Solvent | 1,4-Dioxane | HCID 31275 | — |
| Product | Allylethylamine | HCID 72885 | — |
| Product | N-Ethylprop-2-en-1-amine--hydrogen chloride (1/1) | HCID 20193693 | — |
Reaction Steps
At 10° C. 28.9 g allyl-ethyl-carbamic acid tert-butyl ester (156 mmol) are dissolved in 200 ml 4N HCl in dioxane and slowly warmed to room temperature. When the development of gas has ceased the mixture is warmed at 30° C. for 1 h. The mixture is concentrated under reduced pressure and crystallized from EtOH/TBME to yield the hydrochloric acid salt of allyl ethyl amine as white plates.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07612055B2 |
| Source dataset | uspto-grants-2009_11 |
| ORD ID | ord-a80a7843777b4623b4f0803942946845 |
| Source note | uspto-grants-2009_11 |