hypofluorite → (Fluorooxy)pentafluoroethane

HRID 1433336Notes

Reaction equation

HRID 1433336 reaction equation
F[O-].[C:3]([C:7]([O:10]C(C(Cl)(Cl)F)Cl)([F:9])[F:8])([F:6])([F:5])[F:4].C(C(OC(C(F)Cl)(Cl)Cl)(F)F)(F)(F)[F:18]>>[C:3]([C:7]([O:10][F:18])([F:9])[F:8])([F:6])([F:5])[F:4]

Participants

4

Reactant 3

HCID 46209hypofluoriteHCID 131727729HCID 131727729, compoundHCID 131727730HCID 131727730, compound

Product 1

HCID 12667912(Fluorooxy)pentafluoroethane

Procedure

The reaction is carried out for 3 hours. The raw product (65.0 g) is analyzed by GLC/MS. The hypofluorite conversion is 100% and the selectivity in the two reaction products CF3CF2O—CHCl—CFCl2 and CF3CF2O—CCl2—CHClF is equal to 61%.

Sources & evidence

ORD record
ord-41f2d520d4b54afc80c2a76313e44834
Source dataset
uspto-grants-2009_11
Patent number
US07612242B2

Reaction notes

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