化工社化工社 化学情報印刷レポート · 研究参考用
2-Methoxy-8,9-dihydro-5H-benzo[7]annulen-6(7H)-one → 3-Methoxy-8-(4-methoxy-2-nitrophenyl)-6,7-dihydro-5H-benzocycloheptene
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 2-Methoxy-8,9-dihydro-5H-benzo[7]annulen-6(7H)-one | HCID 12369177 | — |
| 反応物 | Tributyl(4-methoxy-2-nitrophenyl)tin | HCID 23087474 | — |
| 反応物 | HCID 86605238 | HCID 86605238 | — |
| 生成物 | 3-Methoxy-8-(4-methoxy-2-nitrophenyl)-6,7-dihydro-5H-benzocycloheptene | HCID 66626968 | — |
反応手順
Synthesized from 2-methoxy-5,7,8,9-tetrahydrobenzocyclohepten-6-one according to an analogous synthetic method to Preparation Example 82, 2-methoxy-8,9-dihydro-7H-benzocyclohepten-6-yl trifluoromethanesulfonate (3.0 g) and tributyl(4-methoxy-2-nitrophenyl)tin (10.8 g) were used according to an analogous synthetic method to Preparation Example 77 to provide the title compound (2.8 g).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US07612114B2 |
| 出典データセット | uspto-grants-2009_11 |
| ORD ID | ord-da2c626018c74dd2bd3ba753b6f2cbb0 |
| 出典メモ | uspto-grants-2009_11 |