Manganous Acetate → manganese(2+) neodecanoate

HRID 1434500Notes

Reaction equation

HRID 1434500 reaction equation
[C:1]([OH:12])(=[O:11])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][C:7]([CH3:10])([CH3:9])[CH3:8].C([O-])(=O)C.[Mn+2:17].C([O-])(=O)C>>[C:1]([O-:12])(=[O:11])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][C:7]([CH3:8])([CH3:9])[CH3:10].[Mn+2:17].[C:1]([O-:12])(=[O:11])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][C:7]([CH3:8])([CH3:9])[CH3:10]

Participants

3

Reactant 2

HCID 12525Manganous AcetateHCID 62838Versatic 10

Product 1

HCID 22315822manganese(2+) neodecanoate

Conditions

Temperature
140 °C

Procedure

Neodecanoic acid (300 grams) and manganese (II) acetate (106 grams) were both placed into a reaction vessel equipped with a condenser, Dean-stark trap, thermometer, thermocouple, and a gas inlet. Nitrogen gas was bubbled into the reactants. The reactants were heated to 140° C. and stirred for two hours. Overheads and condensate from the reaction were collected in the trap. A subatmospheric pressure was applied to the reaction vessel and the reactants were stirred for an additional two hours at 140° C. until the reaction was complete. Analysis of the product indicated that the product had a kinematic viscosity of 54.8 cSt at 100° C. and a manganese content of 8.1 percent by weight.

Workup

  1. customboth placed into a reaction vessel
  2. customequipped with a condenser, Dean-stark trap
  3. customNitrogen gas was bubbled into the reactants
  4. customOverheads and condensate from the reaction were collected in the trap
  5. stirringthe reactants were stirred for an additional two hours at 140° C. until the reaction
  6. customat 100° C.

Sources & evidence

ORD record
ord-c2a4da2f150f405e874fbb0d85f13c61
Source dataset
uspto-grants-2009_11
Patent number
US07615520B2

Reaction notes

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