HuagongsheHuagongshe Chemistry Print Report · For research reference only
Methane, dichloromethoxy- → 7-Fluoro-2,3-dihydrobenzo[b][1,4]dioxine-6-carbaldehyde
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Methane, dichloromethoxy- | HCID 21004 | — |
| Reactant | 6-Fluoro-2,3-dihydro-1,4-benzodioxine | HCID 12464545 | — |
| Catalyst | Titanium Tetrachloride | HCID 24193 | — |
| Product | 7-Fluoro-2,3-dihydrobenzo[b][1,4]dioxine-6-carbaldehyde | HCID 14644883 | — |
Reaction Steps
7-Fluoro-2,3-dihydrobenzo[1,4]dioxine-6-carboxaldehyde was prepared from 6-fluoro-2,3-dihydrobenzo[1,4]dioxine [V. Daukas et al Chemija, 1999, 10 (1), 59] by reaction of dichloromethyl methyl ether and titanium tetrachloride: LC-MS (ES) m/e 155 (M+H)+.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07618959B2 |
| Source dataset | uspto-grants-2009_11 |
| ORD ID | ord-7534cd4bd6c645a69012985d80ef3e86 |
| Source note | uspto-grants-2009_11 |