HuagongsheHuagongshe Chemistry Print Report · For research reference only
Hydrogen Peroxide → 1,1-Dimethyl-3-(4-cyano-3-(methylsulfinyl)-5-isothiazolyl)urea
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Hydrogen Peroxide | HCID 784 | — |
| Reactant | 1,1-Dimethyl-3-(4-cyano-3-(methylthio)-5-isothiazolyl)urea | HCID 21399275 | — |
| Product | 1,1-Dimethyl-3-(4-cyano-3-(methylsulfinyl)-5-isothiazolyl)urea | HCID 21399285 | — |
Reaction Steps
In the manner of Example II, 7.9 g of 1,1-dimethyl-3-(4-cyano-3-(methylthio)-5-isothiazolyl)urea was oxidized with 3.7 ml of 30% hydrogen peroxide to give 7.0 g of 1,1-dimethyl-3-(4-cyano-3-(methylsulfinyl)-5-isothiazolyl)urea, m.p. 178°-179°. The nmr spectrum was consistent with the assigned structure.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04057416 |
| Source dataset | uspto-grants-1977_11 |
| ORD ID | ord-379b7ec6410f4832a35d1853baaad2bc |
| Source note | uspto-grants-1977_11 |