Chromium(3+) trichloride → HCID 178463915, compound

HRID 1438892Notes

Reaction equation

HRID 1438892 reaction equation
[Cl-].[Cl-].[Cl-].[Cr+3:4].[CH2:5]([N:7]([CH2:10][C:11]1[CH:16]=[CH:15][CH:14]=[CH:13][C:12]=1[Li])[CH2:8][CH3:9])[CH3:6]>>[CH2:5]([N:7]([CH2:10][C:11]1[CH:16]=[CH:15][CH:14]=[CH:13][C:12]=1[Cr:4]([C:16]1[CH:15]=[CH:14][CH:13]=[CH:12][C:11]=1[CH2:10][N:7]([CH2:8][CH3:9])[CH2:5][CH3:6])[C:12]1[CH:13]=[CH:14][CH:15]=[CH:16][C:11]=1[CH2:10][N:7]([CH2:8][CH3:9])[CH2:5][CH3:6])[CH2:8][CH3:9])[CH3:6]

Participants

3

Reactant 2

HCID 6452300Chromium(3+) trichlorideHCID 178506685HCID 178506685, compound

Product 1

HCID 178463915HCID 178463915, compound

Procedure

In Angew. Chem., 75, 94 (1963), Bahr and Zohm disclose reaction of chromium trichloride with 2-diethylaminomethylphenyllithium to give tris(2-diethylaminomethylphenyl)chromium. The product was highly unstable to atmospheric oxygen.

Sources & evidence

ORD record
ord-4dd68dadea7d408cb7a9fbf54f25c9dc
Source dataset
uspto-grants-1977_11
Patent number
US04057565

Reaction notes

Loading…