HuagongsheHuagongshe Chemistry Print Report · For research reference only
Dimethyl Sulfoxide → 5H-Dibenzo(a,d)cycloheptene-2-acetic acid, alpha-methyl-5-oxo-
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Dimethyl Sulfoxide | HCID 679 | — |
| Reactant | HCID 21397491 | HCID 21397491 | — |
| Solvent | Water | HCID 962 | — |
| Product | 5H-Dibenzo(a,d)cycloheptene-2-acetic acid, alpha-methyl-5-oxo- | HCID 173910 | — |
Reaction Steps
0.5 G. of 2-(5-bromo-5H-dibenzo[a,d]cyclohepten-2-yl)propionic acid is dissolved in 10 ml. of dimethylsulfoxide and heated at 150°-180° C. under nitrogen for 2 hours, then cooled, poured into water and worked up as in part A to afford 2-(5H-dibenzo[a,d]cyclohepten-5-on-2-yl)propionic acid.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04059611 |
| Source dataset | uspto-grants-1977_11 |
| ORD ID | ord-0a17b2e2546f4ea5b8efafb0e7d3f870 |
| Source note | uspto-grants-1977_11 |