Ammonium azide → HCID 178438404, compound

HRID 1439465Notes

Reaction equation

HRID 1439465 reaction equation
[C:1]([C:3]1[C:4](=[O:16])[O:5][C:6]2[C:11]([C:12]=1[CH2:13][CH2:14][CH3:15])=[CH:10][CH:9]=[CH:8][CH:7]=2)#[N:2].[N-:17]=[N+:18]=[N-:19].[NH4+]>CCO>[CH2:13]([C:12]1[C:11]2[C:6](=[CH:7][CH:8]=[CH:9][CH:10]=2)[O:5][C:4](=[O:16])[C:3]=1[C:1]1[NH:19][N:18]=[N:17][N:2]=1)[CH2:14][CH3:15]

Participants

4

Reactant 2

HCID 10313046Ammonium azideHCID 21397874HCID 21397874, compound

Product 1

HCID 178438404HCID 178438404, compound

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

The reaction of 3-cyano-4-n-propyl coumarin (41.67 g; 0.196 mole) with ammonium azide as described in Example 1 afforded the title product, m.p. (EtOH) 178°-181° C (Found; C, 61.03; H, 4.95; N, 22.48; C13H12N4O2 requires; C, 60.93; H, 4.72; N, 21.86%).

Sources & evidence

ORD record
ord-f0ca8a83173443b78af0d9713fa11d04
Source dataset
uspto-grants-1977_11
Patent number
US04059704

Reaction notes

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