Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Methanol | HCID 887 | — |
| Reactant | Cyclohexanol | HCID 7966 | — |
| Reactant | 3-Pentenenitrile, Pract. | HCID 20750 | — |
| Product | Cyclohexyl 5-cyanopentanoate | HCID 54021572 | 47.3% |
Reaction Steps
Example 3 is carried out with an equal amount of 3-pentenonitrile in place of 4-pentenonitrile, and with the methanol replaced by 25 parts of cyclohexanol, the mixture is heated to 160° C, and the autoclave is shaken for 4 hours, under a final pressure of 260 bars. 9.9 parts of 5-cyanovaleric acid cyclohexyl ester (47.3% of theory) of boiling point 124.5°-125.5° C/0.5 mm Hg, nD20 = 1.4598, are obtained.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US04060543 |
|---|
| Source dataset | uspto-grants-1977_11 |
|---|
| ORD ID | ord-f61d3112559649c79aacbb508e41e0c3 |
|---|
| Source note | uspto-grants-1977_11 |
|---|
