Acetaldehyde → Acetaldehyde-3,4-ethylenedioxyphenylhydrazone

HRID 1439619Notes

Reaction equation

HRID 1439619 reaction equation
[CH2:1]1[CH2:10][O:9][C:8]2[CH:7]=[CH:6][C:5]([NH:11][NH2:12])=[CH:4][C:3]=2[O:2]1.[CH:13](=O)[CH3:14]>CCOCC>[CH2:1]1[CH2:10][O:9][C:8]2[CH:7]=[CH:6][C:5]([NH:11][N:12]=[CH:13][CH3:14])=[CH:4][C:3]=2[O:2]1

Participants

4

Reactant 2

HCID 177AcetaldehydeHCID 5164485(2,3-Dihydro-benzo[1,4]dioxin-6-yl)-hydrazine

Product 1

HCID 68119945Acetaldehyde-3,4-ethylenedioxyphenylhydrazoneYield 78.3%

Reagents, catalysts & solvents 1

HCID 3283Diethyl EtherSolvent

Procedure

To a solution of 17 g of 3,4-ethylenedioxyphenylhydrazine in 100 ml of ether was added dropwise 11 g of 80 % acetaldehyde at 5° - 10° C over a period of 30 minutes. After stirring for an additional two hours at 5° - 10° C, the ethereal solution was separated, and dried over anhydrous sodium sulfate. The ether was evaporated, and the resultant residue was distilled to give 15.4 g of acetaldehyde-3,4-ethylenedioxyphenylhydrazone having a boiling point of 139° - 142° C (0.15 mmHg).

Workup

  1. customthe ethereal solution was separated
  2. dry with materialdried over anhydrous sodium sulfate
  3. customThe ether was evaporated
  4. distillationthe resultant residue was distilled

Sources & evidence

ORD record
ord-444f436fd7a34590b682def1dac453ac
Source dataset
uspto-grants-1977_11
Patent number
US04060550

Reaction notes

Loading…