HuagongsheHuagongshe Chemistry Print Report · For research reference only
Cyclohexanone → (1,1'-Biphenyl)-2-ol
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Cyclohexanone | HCID 7967 | — |
| Reactant | Potassium Sulfate | HCID 24507 | — |
| Catalyst | Platinum(4+);tetrachloride;hexahydrate | HCID 73357391 | — |
| Catalyst | chloropalladium | HCID 178479784 | — |
| Product | (1,1'-Biphenyl)-2-ol | HCID 7017 | — |
Reaction Steps
The same procedure as in Example 1 is repeated except that in place of 1g of chloroplatinic acid hexahydrate, 2.5g of potassium sulfate and at a rate of 15.5 ml/hr. of cyclohexanone dimer, 1.25g of chloropalladium, 2.0g of potassium sulfate and at a rate of 8.0 ml/hr. are employed. The conversion is found to be always 100% over the reaction period of 2,000 hours. Table 2 gives the selectivity for o-phenylphenol measured.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04060559 |
| Source dataset | uspto-grants-1977_11 |
| ORD ID | ord-958bc36869534ee69a17a532487e72c8 |
| Source note | uspto-grants-1977_11 |