HuagongsheHuagongshe Chemistry Print Report · For research reference only
Ethylenediamine → HCID 21396682, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Ethylenediamine | HCID 3301 | — |
| Reactant | Acrylonitrile | HCID 7855 | — |
| Reactant | 1,5-Bis[4-(propan-2-yl)cyclohexyl]pentan-3-one | HCID 21396647 | — |
| Product | HCID 21396682 | HCID 21396682 | — |
Reaction Steps
As an alternative to obtaining a mixture of Schiff bases VI and VI(a) or VI(b), the reaction can be conducted stepwise. For example, 1,2-diaminoethane may be converted to a Schiff base with 1,5-di-(4-isopropylcyclohexyl)-3-pentanone, catalytically reduced, then the ring nitrogen selectively cyanoethylated with acrylonitrile, followed by catalytic hydrogenation to furnish [1,5-di-(4-isopropylcyclohexyl)-3-pentyl]-1,4,8-triazaoctane.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04060639 |
| Source dataset | uspto-grants-1977_11 |
| ORD ID | ord-3a0d87aa058449b180688ab48e252a21 |
| Source note | uspto-grants-1977_11 |