HuagongsheHuagongshe Chemistry Print Report · For research reference only
Ethanol → Ethyl phenylacetate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Ethanol | HCID 702 | — |
| Reactant | Water | HCID 962 | — |
| Reactant | Benzyl Chloride | HCID 7503 | — |
| Reactant | Sodium Dithionite | HCID 24489 | — |
| Reactant | Sodium ethoxide | HCID 2723922 | — |
| Catalyst | Manganese | HCID 23930 | — |
| Product | Phenylacetic Acid | HCID 999 | 6% |
| Product | Benzyl Chloride | HCID 7503 | — |
| Product | Ethyl phenylacetate | HCID 7590 | 71% |
| Product | Benzyl ethyl ether | HCID 10873 | — |
Reaction Steps
In a manner similar to Example 17, 126.5 g of benzyl chloride, 794 g of a 9 wt-% solution of sodium ethylate in ethanol, 12 g CoCl2.6 H2O, 6 g manganese powder and 1 g Na2S2O4 were reacted with CO. After the usual processing, 8 g of benzyl chloride, 109 g of phenylacetic acid ethyl ester (yield 71%), 8 g of phenylacetic acid (yield 6%) and 1 g of ethylbenzyl ether were isolated.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04060690 |
| Source dataset | uspto-grants-1977_11 |
| ORD ID | ord-eed0a59619294e98b29d2342243aea32 |
| Source note | uspto-grants-1977_11 |