HuagongsheHuagongshe Chemistry Print Report · For research reference only
Hydroquinone → Isooctyl acrylate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Hydroquinone | HCID 785 | — |
| Reactant | Methyl Acrylate | HCID 7294 | — |
| Reactant | 4-Methoxyphenol | HCID 9015 | — |
| Reactant | Dimethyltin dichloride | HCID 12955 | — |
| Reactant | Sodium Hydroxide | HCID 14798 | — |
| Reactant | Isooctan-1-ol | HCID 15450 | — |
| Solvent | Heptane | HCID 8900 | — |
| Product | Isooctyl acrylate | HCID 165746 | 97% |
Reaction Steps
In a similar manner, a mixture of 520.9 parts isooctyl alcohol, 516.6 parts methyl acrylate, 183 parts heptane, 2.4 parts dimethyltin dichloride, 0.5 parts sodium hydroxide (molar ratio 1.14:1), 1.6 parts 4-methoxyphenol and 0.6 parts hydroquinone yielded, after reaction and work up as in Example 1, 715.2 parts (97 percent yield, based on isooctyl alcohol) of isooctyl acrylate with a purity of 99.9 percent, containing no detectable tin.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05498751 |
| Source dataset | uspto-grants-1996_03 |
| ORD ID | ord-8d3d74aefb4f461da25dcb99accfcf27 |
| Source note | uspto-grants-1996_03 |