HuagongsheHuagongshe Chemistry Print Report · For research reference only
Hydroquinone → Phenoxyethyl acrylate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Hydroquinone | HCID 785 | — |
| Reactant | Methyl Acrylate | HCID 7294 | — |
| Reactant | 4-Methoxyphenol | HCID 9015 | — |
| Reactant | Dimethyltin dichloride | HCID 12955 | — |
| Reactant | Phenoxyethanol | HCID 31236 | — |
| Reactant | Sodium Methoxide | HCID 10942334 | — |
| Solvent | Heptane | HCID 8900 | — |
| Product | Phenoxyethyl acrylate | HCID 39485 | 91% |
Reaction Steps
In a similar manner, a mixture of 414.5 parts 2-phenoxyethanol, 388 parts methyl acrylate, 141.6 parts heptane, 4.1 parts dimethyltin dichloride, 1.1 parts sodium methoxide (molar ratio 1.09:1), 1.4 parts 4-methoxyphenol and 0.5 parts hydroquinone yielded 524.8 parts (91 percent yield, based on 2-phenoxyethanol) of 2-phenoxyethyl acrylate with a purity of 98.3 percent, containing no detectable tin.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05498751 |
| Source dataset | uspto-grants-1996_03 |
| ORD ID | ord-eddedbd113144e2cb3347d25eaf899dd |
| Source note | uspto-grants-1996_03 |