HCID 18982512, compound → HCID 18982541, compound

HRID 1440890Notes

Reaction equation

HRID 1440890 reaction equation
[CH2:1]([B-:5]([C:18]1[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=1)([C:12]1[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1)[C:6]1[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1)[CH2:2][CH2:3][CH3:4].[Li+].[Cl-].[CH3:26][S+:27]([CH3:38])[CH2:28][C:29]([C:31]1[CH:36]=[CH:35][C:34]([Cl:37])=[CH:33][CH:32]=1)=[O:30]>O>[CH3:26][S+:27]([CH3:38])[CH2:28][C:29]([C:31]1[CH:32]=[CH:33][C:34]([Cl:37])=[CH:35][CH:36]=1)=[O:30].[CH2:1]([B-:5]([C:18]1[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=1)([C:6]1[CH:7]=[CH:8][CH:9]=[CH:10][CH:11]=1)[C:12]1[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1)[CH2:2][CH2:3][CH3:4]

Participants

4

Reactant 2

HCID 18982512HCID 18982512, compoundHCID 23668465HCID 23668465, compound

Product 1

HCID 18982541HCID 18982541, compoundYield 91.1%

Reagents, catalysts & solvents 1

HCID 962WaterSolvent2×

Procedure

An aqueous solution of 6.10 g of lithium butyltriphenylborate in 100 ml of water was added to a solution of 5.00 g of dimethyl-p-chlorophenacylsulfonium chloride in 100 ml of water, and the resultant mixture was stirred at room temperature for 30 minutes. Then, the reaction mixture was filtered, and the resultant crystal was washed with water and dried to give 9.34 g of dimethyl-p-chlorophenacylsulfonium-butyltriphenylborate as a white crystal.

Workup

  1. filtrationThen, the reaction mixture was filtered
  2. washthe resultant crystal was washed with water
  3. customdried

Sources & evidence

ORD record
ord-6f569b76fa6b46809a5b3954d9e48911
Source dataset
uspto-grants-1996_03
Patent number
US05500453

Reaction notes

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