Water → HCID 18982480, compound

HRID 1440895Notes

Reaction equation

HRID 1440895 reaction equation
[Br-].[CH2:2]([S+:14]([CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH3:35])[CH2:15][C:16]([C:18]1[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=1)=[O:17])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH3:13].[CH2:36]([B-:40]([C:53]1[CH:58]=[CH:57][CH:56]=[CH:55][CH:54]=1)([C:47]1[CH:52]=[CH:51][CH:50]=[CH:49][CH:48]=1)[C:41]1[CH:46]=[CH:45][CH:44]=[CH:43][CH:42]=1)[CH2:37][CH2:38][CH3:39].[Li+].O>C(O)C>[CH2:24]([S+:14]([CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH3:13])[CH2:15][C:16]([C:18]1[CH:19]=[CH:20][CH:21]=[CH:22][CH:23]=1)=[O:17])[CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH3:35].[CH2:36]([B-:40]([C:53]1[CH:58]=[CH:57][CH:56]=[CH:55][CH:54]=1)([C:41]1[CH:42]=[CH:43][CH:44]=[CH:45][CH:46]=1)[C:47]1[CH:52]=[CH:51][CH:50]=[CH:49][CH:48]=1)[CH2:37][CH2:38][CH3:39]

Participants

5

Reactant 3

HCID 962WaterHCID 23668465HCID 23668465, compoundHCID 88360684HCID 88360684, compound

Product 1

HCID 18982480HCID 18982480, compoundYield 68%

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

A mixture of 7.20 g of didodecylphenacylsulfonium bromide and 3.87 g of lithium butyltriphenylborate was stirred in 200 ml of ethanol at room temperature for 30 minutes. The reaction mixture was poured into 1,000 ml of water, and the resultant oily component was separated, recovered, washed with water and dried to give 6.78 g of didodecylphenacylsulfonium-butyltriphenylborate.

Workup

  1. customthe resultant oily component was separated
  2. customrecovered
  3. washwashed with water
  4. customdried

Sources & evidence

ORD record
ord-ea7e63f0267e474b9e1db4f6d62670a3
Source dataset
uspto-grants-1996_03
Patent number
US05500453

Reaction notes

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