Water → HCID 18982589, compound

HRID 1440897Notes

Reaction equation

HRID 1440897 reaction equation
[Br-].[CH2:2]([S+:14](CCCCCCCCCCCC)[CH2:15][C:16]1[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=1)[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH3:13].[CH2:34]([B-:38]([C:51]1[CH:56]=[CH:55][CH:54]=[CH:53][CH:52]=1)([C:45]1[CH:50]=[CH:49][CH:48]=[CH:47][CH:46]=1)[C:39]1[CH:44]=[CH:43][CH:42]=[CH:41][CH:40]=1)[CH2:35][CH2:36][CH3:37].[Li+].O>C(O)C>[CH2:2]([SH+:14][CH2:15][C:16]1[CH:17]=[CH:18][CH:19]=[CH:20][CH:21]=1)[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH3:13].[CH2:34]([B-:38]([C:51]1[CH:56]=[CH:55][CH:54]=[CH:53][CH:52]=1)([C:39]1[CH:40]=[CH:41][CH:42]=[CH:43][CH:44]=1)[C:45]1[CH:50]=[CH:49][CH:48]=[CH:47][CH:46]=1)[CH2:35][CH2:36][CH3:37]

Participants

5

Reactant 3

HCID 962WaterHCID 23668465HCID 23668465, compoundHCID 88360367HCID 88360367, compound

Product 1

HCID 18982589HCID 18982589, compoundYield 82.1%

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

A mixture of 6.30 g of didodecylbenzylsulfonium bromide and 3.56 g of lithium butyltriphenylborate was stirred in 200 ml of ethanol at room temperature for 30 minutes. The reaction mixture was poured into 1,000 ml of water, and the resultant oily component was separated, recovered, washed with water and dried to give 5.66 g of dodecylbenzylsulfonium-butyltriphenylborate.

Workup

  1. customthe resultant oily component was separated
  2. customrecovered
  3. washwashed with water
  4. customdried

Sources & evidence

ORD record
ord-1f50ea44697442259afd0ce0a9c28cfa
Source dataset
uspto-grants-1996_03
Patent number
US05500453

Reaction notes

Loading…